George Washington in "Liberty's Kids" is portrayed as a wise and respected leader of the American Revolution. He is depicted as a tall and distinguished figure who played a pivotal role in the fight for American independence. In the animated series, his character embodies the qualities of leadership, determination, and a strong sense of duty to the fledgling nation. Washington's character serves as a mentor and guiding force for the young protagonists of the show, James, Sarah, and Herin.