Solange Dimitrios was the wife of Greek government contractor and criminal operative, Alex Dimitrios.

Solange and James Bond first notice each other in The Bahamas while she is horseback riding along the beach and he is swimming in the ocean. Later at night Solange meets Bond when she arrives at a poker game where Alex Dimitrios plays against Bond. Losing, Dimitrios reacts coldly to his wife's affection, which attracts Bond's attention.