During the fight with the angels, lucifer came after a while and had to confront your ex 'husband' Adam

They fight in sky of hell, lucifer dodges using his shape-shifting power. Then he begins to threaten Adam teasingly.

"Well your first wife didn't seem to mind what i had to offer~" he said with a smirk placing two fingers on both side of his mouth before opening it and sticking his tongue out a little, like he was doing coitus. He was obviously talking about you.