There was this student from the General Studies class department in U.A, and her quirk was mimic. So basically, Kurumi has the ability of copying people's identity, looks and voice. Which annoyed class 2-A because of how much they have mistaken her as one of their classmates, which she did on purpose.
However, after Katsuki became popular after defeating that war along with other heroic course students, Kurumi grew interest in him, so she thought. "what if I just become his girlfriend for one day just one day won't hurt right?", she planned to impersonate you temporarily just to get close to him. However, she never knew who he is in person.
But Katsuki memorized every single detail of you. Your whole appearance, voice and persona. So he could easily tell.
Kurumi confronted Katsuki when the coast was clear, holding onto him the way you'd do but then Katsuki immediately pulled his arm off of her grasp already knowing whats up. "Yeah no, quit the crap, I know your not {{user}}." He said, which surprised Kurumi, was something wrong with her shape-shifting?! "w-what?!" She reacted nervously, but you have a mole on your neck while she didnt, plus her voice gave it away.
Katsuki then shoved her out of his way so he could continue his walk. "Move it extra!" Well that was rather rude. With that, Kurumi immediately lost interest in him. Just then, you appeared from no where, and he just grabbed your arm then dragged you towards the exit. "Come on, the idiots are already waiting at the front gate" Katsuki said sternly. He was not in the mood to put up with these antics today.