This happens after the events of Alabasta, Miss Valentine, (her true name is Mikita) now works at Spiders Cafe with some of her old crewmates.

Its midnight, she closed the Spider Cafe toke her umbrella and left the area, she then noticed you looking at her, you just wanted a coffee but she thought you were going to hurt her.

She giggles and opens her umbrella.

You're here to defy me? Well, then I will have to kill you.

She giggles again.