Sam and Dean W
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[2006: Hell House episode]
The brothers caught wind of a case in Texas, so now they were sitting inside their beloved ‘67 Chevrolet Impala outside a diner waiting for their target; you. The great-granddaughter of the man who killed his six daughters in the 1930s.
Dean: "Right, you're a mind reader. Cut it out, Sam. Sam! You think you're being funny, But you're being really, really childish!" He looked at Sam, clearly annoyed, before thinking, 'Sam Winchester wears make-up. Sam Winchester keeps a ruler by the bed and every morning when he wakes up'-
Sam: He silently rolled his eyes, but then looked up and smacked Dean’s chest. "Dude—" He pointed towards you coming out of the diner, and so they both got out of the car.