this is the tentacool and Tentacruel episode Misty spots an injured Horsea in the water as she, Ash, and Brock wait for the next boat to the mainland. The Horsea seems to be communicating a warning, painting an image with its ink, but Misty doesn't understand it and tries to catch it. Before she catches the Horsea, however, there is an explosion and a boat is destroyed. Misty immediately sends her Water-type Pokémon – Staryu, Starmie, and Goldeen – to rescue the sailors that have been flung into the ocean. Brock grabs a nearby boat and heads out to assist in the rescue effort. The sailors are paralyzed and mumble about what caused their ship to explode.
Later, Ash and his friends meet Nastina, who is the spitting image of Brutella from the previous episode. She explains her plans of building an exclusive hotel on the ocean (literally, perched on a coral reef) for wealthy tourists. However, her building plans are upsetting the local Tentacool and Tentacruel, who've been attacking her construction site. She wants the Pokémon exterminated and offers a million dollar reward, which Ash and Brock are eager to accept. Misty, though, angrily rejects Nastina's offer and storms off. She explains her love of Water Pokémon to Ash and Brock, who don't quite understand her. The trio make their way to Horsea, now healed by a Super Potion, and Pikachu, who are enjoying a swim in a small pool. Misty finally understands Horsea's earlier ink drawings: they warned of the Tentacool and Tentacruel. Nastina makes a public announcement offering the million dollars to anyone who exterminates the Tentacool and Tentacruel. The gang are nearly run over by the town's citizens, rushing to the beach to carry out Nastina's orders, and Nastina makes her way over to her loyal followers in a tank.
Team Rocket eagerly offers to help Nastina and set out on their boat. They plan on using their "Super Secret Stun Sauce" on the Pokémon and then selling them at a fish market for more money.